If the $w_i$ are nonnegative, then recast the problem probabilistically: You have a random variable $X$ that takes value $x_i$ with probability $w_i$. Then the inequality is equivalent to
$$
E(X^4)-E(X)E(X^3)\ge0
$$
which follows from the fact that $X$ and $X^3$ are positively (ok, not-negatively) correlated (draw a picture!), and therefore
$$
0\le \operatorname{Cov}(X,X^3) = E(XX^3)-E(X)E(X^3).
$$
More rigorously, the general result is: If $h$ is a nondecreasing function, then $\operatorname{Cov}(X,h(X))\ge0$.
Proof:
By definition,
$$\operatorname{Cov}(X,h(X)):=E(X-EX)(h(X)-Eh(X)).$$
Write
$$(X-EX)(h(X)-Eh(X))=(X-EX)(h(X)-h(EX)) + (X-EX)(h(EX)-Eh(X))\tag1
$$
The first term on the RHS of (1) is a nonnegative random variable, since $h$ is nondecreasing. The second term has expectation zero since $h(EX)$ and $Eh(X)$ are both constant.