There is a notion of "asymptotic dimension", defined for all metric spaces, which for $\mathbb{H}^n$ (or the Euclidean $n$-space) equals $n$ ($*$). It is monotone under coarse embeddings. In particular, $\mathbb{H}^n$ does not coarsely embed into $\mathbb{H}^m$ if $n>m$.
This latter fact does not follow from the Gromov boundary, because the latter is not functorial for coarse embedding (from the latter one gets a weaker statement, since anyway it's functorial for QI-embeddings: $\mathbb{H}^n$ does quasi-isometrically embed into $\mathbb{H}^m$ for $n>m$ (and in particular they are not quasi-isometric, as mentioned by Paul).
Also, $\mathbb{H}^n$, $n\ge 2$ does not coarsely embed into the free group: this follows from asymptotic dimension (which is 1 for the free group). An easier way to see that they are not quasi-isometric consists in using that the space of ends is a Cantor space in the first case an a point for $\mathbb{H}^n$. Since the space of ends is functorial for coarse embeddings, this probably can help show that $\mathbb{H}^n$ does not coarsely embed into a free group but it doesn't seem to follow from a purely formal argument.
The boundary can be useful beyond its topology. For instance, the negatively curved symmetric spaces $\mathbb{H}^{2n}$ and $\mathbb{H}^n(\mathbf{C})$ are not quasi-isometric, although they have the same number of ends (1), the same asymptotic dimension ($2n$) and homeomorphic Gromov boundaries (a $(2n-1$)-sphere). The point is that their Gromov boundaries are not quasi-symmetrically equivalent.
($*$) I can only provide references, it's not obvious. In Chapter 10 of Buyalo-Schroeder's book, it's proved that the asymptotic dimension of a $n$-dimensional Hadamard manifold is $\ge n$. This applies to both the Euclidean and the real hyperbolic space.
In the same book they only provide non-sharp upper bounds. But Higes-Peng (arXiv link), Assouad-Nagata dimension of connected Lie groups. Math. Z. 273 (2013), no. 1-2, 283–302. proved that the asymptotic Assouad-Nagata (aAN) dimension of a connected Lie group $G$ with maximal compact subgroup is $\dim(G/K)$, this applies in particular to the connected part of the isometry group of any $n$-dimensional isometry-homogeneous contractible Riemannian manifold to show that its aAN dimension is $\le n$. It it trivial from the definition that the aAN dimension is an upper bound for the asymptotic dimension.
Combining, the asymptotic dimension (and the aAN dimension) of any homogeneous Hadamard manifold is $n$.