If $M$ is a closed, connected, oriented manifold, let $\|M\|$ denote its Gromov norm (also known as simplicial volume). One of the key properties of the Gromov norm is that if $N$ is another closed, connected, oriented manifold of the same dimension, then for any continuous map $f : M \to N$, the degree of $f$ satisfies
$$|\deg f|\|N\| \leq \|M\|.$$
In particular, if $f : M \to M$, then either $\|M\| = 0$ in which case we get no information about the degree of $f$, or $\|M\| \neq 0$ and so $|\deg f| \leq 1$, i.e. $\deg f \in \{-1, 0, 1\}$.
Gromov proved that the Gromov norm of a closed oriented hyperbolic manifold $M$ of dimension $n$ satisfies
$$\|M\| = \frac{\operatorname{vol}(M)}{\nu_n}$$
where $\nu_n$ is the supremal volume of all geodesic $n$-simplices in hyperbolic $n$-space (which is finite). In particular, $\|M\| > 0$.
For $g \geq 2$, the surface $\Sigma_g$ is hyperbolic and hence $\|\Sigma_g\| \neq 0$. So by the above, any map $f : \Sigma_g \to \Sigma_g$ has degree $-1$, $0$, or $1$.
In fact, as $\Sigma_g$ is hyperbolic for $g \geq 2$, it admits a metric of constant Gauss curvature $-1$, so by Gauss-Bonnet
$$\operatorname{vol}(\Sigma_g) = \int_{\Sigma_g}1 = -\int_{\Sigma_g}-1 = -2\pi\chi(\Sigma_g) = -2\pi(2 - 2g) = (4g - 4)\pi.$$
As $\nu_2 = \pi$, we see that $\|\Sigma_g\| = 4g - 4$.
In contrast, $S^2$ and $S^1\times S^1$ admit self-maps of any degree, so their Gromov norm is zero.