Consider the origin of axes situated in one of the foci. It is known (https://17calculus.com/conics/polar/) that, up to a rotation that doesn't change the eccentricity $e$, the polar equation of a hyperbola can be taken as:
$$\tag{1}p=\dfrac{k}{1-e \sin(\theta)}$$
where $e$ is its eccentricity.
(1) is undefined for values of $\theta$ such that:
$$\tag{2}1-e \sin(\theta)=0$$
which, precisely correspond to the directions of asymptotes (directions where "$r$ is infinite").
Let us define $\theta_0$ as the unique angular value in $(0, \dfrac{\pi}{2})$ such that :
$$\tag{3}1-e \sin(\theta_0)=0$$
(explanation : for a hyperbola, $e>1 \ \implies \ \tfrac{1}{e}<1$ ; and $\sin$ function is bijective from $(0, \dfrac{\pi}{2})$ to $(0,1)$.)
Now by hypothesis, we also have a zero value in (2) for $\theta_0+\dfrac{\pi}{3}$:
$$\tag{4}1-e \sin(\theta_0+\dfrac{\pi}{3})=0$$
Subtracting (3) from (4), we get :
$$\tag{4}\sin(\theta_0+\dfrac{\pi}{3})=\sin(\theta_0)$$
from wich we conclude that $\theta_0+\dfrac{\pi}{3}=\pi-\theta_0$, i.e.,
$$\tag{5}\theta_0=\dfrac{\pi}{3}.$$
Plugging (5) into (3) gives
$$e=\dfrac{2}{\sqrt{3}} \approx 1.155$$