I have the same question as this one from a long time ago. Is there an easy way to see that the Killing form on $\mathfrak{sp}(2n)$ is $\kappa(x,y) = (4n+2) \mathrm{tr}(xy)$?
For example, the Killing form for $\mathfrak{sl}(n)$ can be found from the easier to calculate case of $\mathfrak{gl}(n)$ using the decomposition $$\mathfrak{gl}(n) = \mathfrak{sl}(n) \oplus \mathbb{C}.$$ I don't know a similar argument for $\mathfrak{sp}(2n)$ though.