Let's change the notation a little, to make things easier to read. Instead of a function $x \mapsto f(x)$, let's consider a function $t \mapsto x(t)$, and let's use dots to denote differentiation with respect to $t$.
Then the curvature of $x$ is given by
$$
\kappa(t) = \frac{\ddot x}{\sqrt{1 + {\dot x}^2}}
$$
and the derivative of curvature is
$$
\dot\kappa = \frac{d\kappa}{dt} = \frac{\dddot x(1+ {\dot x}^2 ) - \dot x \ddot x^2 } { ({1 + {\dot x}^2})^{3/2} }
$$
So, we can say the following:
- If $\dddot x > 0$ and $\dot x < 0$, then $\dot\kappa > 0$, so $\kappa$ is increasing, so radius of curvature is decreasing
- If $\dddot x < 0$ and $\dot x > 0$, then $\dot\kappa < 0$, so $\kappa$ is decreasing, so radius of curvature is increasing
So, the sign of $\dddot x$ gives us some information about growth of curvature in some situations, at least.
But, in the unfortunate regions where $\dddot x > 0$ and $\dot x > 0$, or where $\dddot x < 0$ and $\dot x < 0$, this line of reasoning doesn't tell us anything about curvature, as far as I can see.
So, it's not quite as simple as I indicated in my original (lazy) answer. Thanks to @TedShifrin for pointing out the error in my reasoning.