Let $$Z=e^{-(-2)^{2/3}}$$Note that
$$-2=2e^{(2k+1)i\pi}$$
let
$$z=(-2)^{2/3}=\sqrt[3]{4}e^{i\pi/3},\sqrt[3]{4}e^{i\pi},\sqrt[3]{4}e^{5i\pi/3}$$
$$e^{i\theta}=\cos\theta+i\sin\theta$$
Now $z$ has $3$ values,
$$z=-\sqrt[3]{4} \,\, ,\,\,
\sqrt[3]{4}\left[\cos\left(\frac{i\pi}{3}\right)+i\sin\left(\frac{i\pi}{3}\right)\right] \,\, ,\,\,
\sqrt[3]{4}\left[\cos\left(\frac{5i\pi}{3}\right)+i\sin\left(\frac{5i\pi}{3}\right)\right]$$
Now writing $Z=e^{-z}$ in the form $a+bi$ is lengthy task but you can notice that as you pointed out there is a real value of $Z$ given as
$$Z=e^{-(-\sqrt[3]{4})}=e^{\sqrt[3]{4}}$$ but we should not ignore other values of $z$ and which will yield complex(pun intended here!) values of $Z=e^{-z}$