Prove and use the following two lemmas:
Lemma. A connected and locally path-connected$\dagger$ space is path-connected.
When a space is locally connected, the path components are open. So if $C$ is a path component, it's open, and its complement is a union of other path components, which are open so $C$ is closed too.
Lemma. A simplicial complex is locally path-connected.
A simplicial complex is locally homeomorphic to $\mathbb{R}^k \times [0,\infty)^{n-k}$.
$\dagger$ A space is locally path-connected when every point has a basis of path-connected neighborhoods.