The complex conjugate of the polar form of a complex number is given by $$\overline{re^{i\theta}}=re^{-i\theta}.$$
To see why, use Euler's formula:
\begin{align}
\overline{r(\cos\theta+i\sin\theta)}&=\overline{r}\ \overline{(\cos\theta+i\sin\theta)}\\
&=r\,(\cos\theta-i\sin\theta)\\
&=r\,(\cos(-\theta)+i\sin(-\theta))\quad\text{[since cosine is even and sine is odd]}\\
&=r\,e^{-i\theta}.
\end{align}
So you can find the conjugates of your $z$ without converting first to rectangular form.
Of course, if you do want to convert from polar to rectangular form, just use Euler's formula employed above:
$$z=re^{i\theta}=r(\cos\theta+i\sin\theta)$$
which can be converted to rectangular form $z=a+bi$ via $$a=r\cos\theta,\quad b=r\sin\theta,$$ which in your case leads to $a=2\cos(3\pi/4)=-\sqrt 2$ and $b=2\sin(3\pi/4)=\sqrt 2$. So $$z=2e^{i{3\pi\over 4}}=-\sqrt{2}+i\sqrt{2}\implies \overline{z}=2e^{-i{3\pi\over 4}}=-\sqrt{2}-i\sqrt{2}.$$ You can do the other one.