$\def\r{\mathrel{\rm R}}$Remember that in proof problems, correct logic and clear setting out are both vital.
Reflexive. For any integer $a$ we have $5\mid 5a$ by definition of divisibility. This can be written as
$$5\mid (a+4a)\ ,$$
and therefore $a\r a$. Thus $\r$ is reflexive.
Symmetric. Let $a,b$ be integers and suppose that $a\r b$. By definition, this means that
$$5\mid(a+4b)\ .$$
But clearly $5\mid5(a+b)$, and so by well-known properties of divisibility,
$$5\mid(5(a+b)-(a+4b))\ ,$$
that is,
$$5\mid(b+4a)\ .$$
Thus $b\r a$. We have proved that if $a\r b$ then $b\r a$; so $\r$ is symmetric.
Transitive. The layout of the proof will be similar to the proof that $\r$ is symmetric (though of course the content will be different). Please try it for yourself.
Equivalence classes. For example, the equivalence class of $1$ is by definition the set of all $a$ such that $a\r1$; that is, the set of all $a$ such that $5\mid(a+4)$. This divisibility statement can be written $a+4=5k$, or $a=5k-4$. So the equivalence class of $1$ is
$$[1]=\{5k-4:k\in{\Bbb Z}\}=\{\ldots,-9,-4,1,6,11,16,\ldots\}\ .$$
If you work out the rest for yourself I think you will soon realise that this relation is in fact just congruence modulo $5$, written in a slightly disguised way.
Good luck!