Let $\mathbb{R} \supset E \neq \varnothing$. Put $\alpha = \sup E $. Then, for all $n \in \mathbb{N}$, $\alpha - \frac{1}{n} $ is not an upper bound of $E$, but $\alpha + \frac{1}{n}$ is an upper bound.
Solution
We have $\frac{1}{n} > 0 $ for all $n \in \mathbb{N}$. Suppose there is some $n_0 \in \mathbb{N}$ such that $\alpha - \frac{1}{n_0}$ is an upper bound of $E$. By definition, we have
$$ \alpha \leq \alpha - \frac{1}{n_0} < \alpha \implies \alpha < \alpha $$
Contradiction. $\alpha + \frac{1}{n}$ is obvious an upper bound of $E$ since $\alpha < \alpha + \frac{1}{n} $ for all $n$.