Let $ a$ be the diameter of circle touching y-axis at the origin.
$\psi$ is the required angle and so on basis of $\psi$, all areas are computed.
$ \dfrac{\sin(\psi)} {r} = \dfrac{1}{a} $ ...(1*)
$ \psi^ {'} = \dfrac{1}{a} $...(2*)
Curvature $ k_g = \sin (\psi)/ r + \psi^{'} = 1/a + 1/a =2/a $...(3*)
where primes are with respect to arc length.
$ \dfrac{dA}{d\psi} = \dfrac{r^2}{2} \dfrac{d\theta}{ds} \dfrac{ ds}{d\psi} $ ...(4*)
$ A = \int_\psi ^{\pi/2} \sin^2(\psi)* a^2/2 * d\psi $..(5*)
$ a^2/2 * ( \pi/4 -( \psi/2 - \sin(2 \psi)/4 ) = \pi (a/2)^2 *\frac{1}{12} $...(6*)
Remaining area fraction is $ \frac{1}{12}$ because portions $ \frac{5}{12}$ is situated above and $ \frac{1}{2}$ in semi-circle below.
The equation numerically solves to $ \psi =82.4566 $ degrees, an option not among those given.