Well, this function has an uncountable number of discontinuities, so it should not be Riemann Integrable (assuming that same result holds for functions from $\mathbb R ^2$ as well as it does for $\mathbb R$
It is discontinuous on the entire diagonal of $[0,1]^2$, since as you approach the diagonal when $x<y$, you get the $\arctan (-\infty)=-\pi /2$, whereas when you approach it when $x>y$, you get $\arctan(\infty )=\pi /2 $, neither of which is 0., and for a function to be Riemann integrable you must have at most a countable number of discontinuties.