For an exact sequence $A\rightarrow B\rightarrow C\rightarrow D\rightarrow E$ show that $C=0$ iff the map $A\rightarrow B$ is surjective and $D\rightarrow E$ is injective.
For $(C=0)$ implies ($A\rightarrow B$ is surjective and $D\rightarrow E$ is injective), ok because $Im(A\rightarrow B)=Ker(B\rightarrow 0)=B$ hence $A\rightarrow B$ is surjective and $Ker(D\rightarrow E)=Im(0\rightarrow D)=0$ hence $D\rightarrow E$ is injective.
I don't know for ($A\rightarrow B$ is surjective and $D\rightarrow E$ is injective) implies ($C=0$).
If I show this, I can conclude that $H_{n}(X,A)=0$ iff $H_{n}(X)\simeq H_{n}(A)$. Thank you !