Imagine the following array:
$$\begin{array}[cccccccccc] .1 && 2 && 3 && 4 && \ldots && n-2 && n-1 && n \\ 2n && 2n-1 && 2n-2 && 2n-3 && \ldots && n+3 && n+2 && n+1\end{array}$$
Notice that each column sums to $2n+1$ and all of the numbers from $1$ to $2n$ are used in the array. There are $n$ columns. What you want to prove is that if you were to highlight $n+1$ numbers in this array (i.e. the elements of $T$), there would be a whole column highlighted, and that pair would sum to $2n+1$.
The pidgeonhole principle essentially says that we cannot possibly highlight $n+1$ numbers such that no two lie in the same column, if there are but $n$ columns. If you want to see this, then just take a small array, like for $n=3$:
$$\begin{array}.1 && 2 && 3\\6 && 5 && 4\end{array}$$
Now, let's start highlighting some numbers, trying to avoid putting two in a column. Our goal is to highlight $4$ numbers, as that is the size of the set $T$. We could start by putting $1$ in $T$:
$$\begin{array}.\color{red}1 && 2 && 3\\6 && 5 && 4\end{array}$$
but now we know we can't put $6$ in $T$ too, because that would sum to $2n+1$. So we might choose $5$ as our next number, forbidding $2$ and we might choose $4$ as the number after that:
$$\begin{array}.\color{red}1 && 2 && 3\\6 && \color{red}5 && \color{red}4\end{array}$$
So, now we have a highlighted number in every column- and adding any further number to the set $T$ would create a pair summing to $7$. But this means that we can't have a fourth element in $T$, at least given how we started - and the pidgeonhole principle guarantees that we can never choose a set of size $4$ without putting two elements in one column.
The key point here is that we should imagine that, as we're creating $T$, we're not choosing numbers to put in it, we're choosing which column to take the numbers from. There are $n$ columns, and we need to make $n+1$ choices - thus we will, at some point, choose the same column twice, and in this context, that means we need to have both elements of some column in $T$, and this forms a pair summing to $2n+1$.