a) For every man $a$ there is a woman $b$ such that $b$ is the mother of $a$.
b) There is a woman $d$ such that for every man $c$, $d$ is the mother of $c$.
The first says that every man has a mother. This is true.
The second says that there is one woman who is every man's mother, that every man has the same mother. This is false.
This is because when we interpret quantifiers (like “for every” and “there is”) we understand that the choices in the later quantifiers can depend on the choices in the earlier quantifiers, but not the other way around.
So the identity of woman $b$ can depend on the choice of the man $a$, and we can have a different $b$ for each $a$.
But the identity of the woman $d$ cannot depend on the choice of the man $c$. It must be the same $d$ for every $c$.