The result in the question is first proved by J.E. Littlewood in Comptes Rendus de l'Academie des Sciences, June 1914.
The result is expressed as:
$$\pi(x)-Li(x)<-K\frac{\sqrt{x}\log\log\log x}{\log x} $$
$$\pi(x)-Li(x)>K\frac{\sqrt{x}\log\log\log x}{\log x}. $$
He concludes that the inequality $\pi(x)<Li(x),$ "presumed by many authors for empirical reasons, cannot obtain for any value of $x$ however large."
He does not specify K.
His conclusion may be interpreted to mean that for any value of $x,$ however large, for which one sense of the inequality holds, one can find a larger $x$ for which the other sense holds, and so on.
Ingham's later proof is somewhat easier (The Distribution of Prime Numbers, Ch. V).