Some relevant facts: $\sin\pi = 0$, and $\sin x$ is a continuous function of $x$.
This tells us that
$$\lim_{x\to\pi} \sin x = 0.$$
Clearly as $n\to\infty$, then $\pi_n \to \pi.$
After all, $|\pi_n - \pi| < 10^{-n}.$
So altogether you have
$$\lim_{n\to\infty} (\pi_n + \sin \pi_n)
= \lim_{x\to\pi} (x + \sin x)
= \left(\lim_{x\to\pi} x\right) + \left(\lim_{x\to\pi} \sin x\right)
= \pi + 0 = \pi.$$
So you should expect $\pi_n + \sin \pi_n$ to converge to $\pi$ eventually.
As you noticed, it seems to converge a lot faster than $\pi_n$ itself converges to $\pi$.
That's because for $x \approx \pi$, $\sin x$ is an excellent approximation of $\pi - x$,
and of course $x + (\pi - x) = \pi.$