Let $X_i$ be the generators of $SU(2)$ and let the parameters of the rotation be $\theta, \phi, \delta$ such that the matrix $R = e^{i(\phi X_{1} + \delta X_{2} + \theta X_{3})}$, where $R$ is an element of $SU(2)$.
So, $R = 1 + i(\phi X_{1} + \delta X_{2} + \theta X_{3}) + \frac{1}{2!}[i(\phi X_{1} + \delta X_{2} + \theta X_{3})]^2 + ...$ via Taylor expansion about the zero matrix $\textbf{0}$.
So, $-i \frac{\partial R}{\partial \phi}|_{\theta, \phi, \delta = 0} = -i\ [iX_{1} + (i \phi X_{1}+i \delta X_{2} + i \theta X_{3})(i X_{1}) + ...]|_{\theta, \phi, \delta = 0} = X_{1}$, and similarly $-i \frac{\partial R}{\partial \delta}|_{\theta, \phi, \delta = 0} = X_{2}$, and $-i \frac{\partial R}{\partial \theta}|_{\theta, \phi, \delta = 0} = X_{3}$.
Therefore, $X_{1} = -i \frac{\partial R}{\partial \phi}|_{\theta, \phi, \delta = 0} = -i \frac{\partial}{\partial \phi}\begin{pmatrix}a & b \\ -b^* & a^* \end{pmatrix}|_{\theta, \phi, \delta = 0} = -i \frac{\partial}{\partial \phi}\begin{pmatrix}e^{i\theta}cos \phi & e^{i\delta}sin \phi \\ -e^{-i\delta}sin \phi & e^{-i\theta}cos \phi \end{pmatrix}|_{\theta, \phi, \delta = 0} = -i \begin{pmatrix}-e^{i\theta}sin \phi & e^{i\delta}cos \phi \\ -e^{-i\delta}cos \phi & -e^{-i\theta}sin \phi \end{pmatrix}|_{\theta, \phi, \delta = 0} = -i \begin{pmatrix}0 & 1 \\ -1 & 0 \end{pmatrix} = \begin{pmatrix}0 & -i \\ i & 0 \end{pmatrix}$, which is one of the Pauli matrices.
But, $X_{2} = -i \frac{\partial R}{\partial \delta}|_{\theta, \phi, \delta = 0} = -i \frac{\partial}{\partial \delta}\begin{pmatrix}a & b \\ -b^* & a^* \end{pmatrix}|_{\theta, \phi, \delta = 0} = -i \frac{\partial}{\partial \delta}\begin{pmatrix}e^{i\theta}cos \phi & e^{i\delta}sin \phi \\ -e^{-i\delta}sin \phi & e^{-i\theta}cos \phi \end{pmatrix}|_{\theta, \phi, \delta = 0} = -i \begin{pmatrix}0 & ie^{i\delta}sin \phi \\ ie^{-i\delta}sin \phi & 0 \end{pmatrix}|_{\theta, \phi, \delta = 0} = -i \begin{pmatrix}0 & 0 \\ 0 & 0 \end{pmatrix} = \begin{pmatrix}0 & 0 \\ 0 & 0 \end{pmatrix}$. But, I don't think that the zero matrix is one of the generators of the $SU(2)$ group. In fact, it is not even a Pauli matrix. I was wondering if someone can point out the error in my calculation of $X_{2}$.