I don't know how to prove the identity using the binomial theorem and I provide a proof using induction (thus the proof may be longer).
Let $S_r = \sum_{k=r}^{\infty}{k-1 \choose r-1}p^rq^{k-r}$. We only need to prove $\forall r \geq 1, S_r = 1$ since by convention, the binomial coefficient is defined as 0 when the lower index is negative.
basis: $S_1 = \sum_{k=1}^{\infty}{k-1 \choose 0}pq^{k-1} = p\sum_{k=0}^{\infty}q^k=p\cdot\frac{1}{1-q}=1$
induction: Assume $S_r = 1, r \geq 1$.
$ \quad S_{r+1}\\
=\sum_{k=r+1}^{\infty}{k-1 \choose r}p^{r+1}q^{k-r-1}\\
=\sum_{k=r+1}^{\infty}{k-2 \choose r-1}p^{r+1}q^{k-r-1} + \sum_{k=r+1}^{\infty}{k-2 \choose r}p^{r+1}q^{k-r-1}\\
=\sum_{k=r}^{\infty}{k-1 \choose r-1}p^{r+1}q^{k-r} +
\sum_{k=r+1}^{\infty}{k-2 \choose r}p^{r+1}q^{k-r-1}\\
=pS_r+
\sum_{k=r+1}^{\infty}{k-2 \choose r}p^{r+1}q^{k-r-1}\\
=pS_r+\sum_{k=r}^{\infty}{k-1 \choose r}p^{r+1}q^{k-r}\\
=pS_r+q(S_{r+1}+{r-1\choose r}p^{r+1}q^{-1})\\
=pS_r+qS_{r+1}=p+qS_{r+1}$
thus $S_{r+1}=1$. QED.
The second equality comes from the addition identity of binomial coefficients, say, ${r \choose k}={r-1 \choose k}+{r-1\choose k-1}$.