Here is a way to do it with the cosine rule. It's very long but if you are not getting the right answer you could try this method.
First, find the intercept of the two equations:
$4x+2=−x+3, x=0.2, y=4(0.2)+2, y=2.8, (0.2, 2.8)$
Now, sub in any y value into both the equations and find the coordinates. I will be using 10 as an example.
Eqn 1: $10=4x+2, x=2, (2,10)$
Eqn 2: $10=-x+3, x=-7, (-7,10)$
Then, find the distance between all three of the points. These three distances will be used subbed in the cosine rule so make sure that the distance that does not connect to the intercept point is $a$
$a$: $2-(-7)=9$
$b$: $\sqrt{(10-2.8)^2+(2-0.2)^2}=7.42$
$c$: $\sqrt{(10-2.8)^2+(-7-0.2)^2}=10.18$
Sub the values into the formula $cos(\theta)=\frac{b^2+c^2-a^2}{2bc}$
$\theta=cos^{-1}(\frac{(7.42)^2+(10.18)^2-(9)^2}{2(7.42)(10.18)})=59°$(approximate answer)