Many of the symbols you list, unless they have meanings I'm unaware of, are meaningless in this context. In general:
$=$ means, as I assume you know, is 'equal to' (there is a certain subtlety here, but I'm hoping you don't want to go into it).
$\approx$ means 'approximately equal to.'
$\sim$ means, in the contexts I'm aware of, 'is asymptotic to,' typically as the arguments go to infinity (although it can be any other value).
$\cong$ and $\equiv$ both mean 'are congruent to' (once again, in the contexts I know).
For a more comprehensive list and explanation, see this Wikipedia page.