Let $A$ be a ring and $M,N,K$ are modules over $A$. Let $\xi\in\text{Ext}_A^1(N,M)$ and $\eta\in\text{Ext}_A^1(K,N)$ are given by
$$\xi:\,\,\,0\to M\to X\to N\to0,$$ $$\eta:\,\,\,0\to N\to Y\to K\to0.$$
Then $$\eta\xi:\,\,\,0\to M\to X\to Y\to K\to0$$ is an element in $\text{Ext}_A^2(K,M)$.
My questions is, what are the necessary and sufficient conditions for $\xi$ and $\eta$ to have a zero product in $\text{Ext}^2$?
What is the definition of element being zero in $\text{Ext}^2$?