Use contour integration.
Case 1: $t>0$
Observe the integral over $C$, where $C$ is comprised of the real line plus an infinite semi-circle, $C_{\infty}$, enclosing the upper-half plane of the complex $\omega $ plane.
$$\frac{1}{2\pi}\oint_C\frac{e^{i\omega t}}{a+i\omega}d\omega=\frac{1}{2\pi}\int_{-\infty}^{\infty}\frac{e^{i\omega t}}{a+i\omega}d\omega+\int_{C_{\infty}}\frac{e^{i\omega t}}{a+i\omega}d\omega$$
Use of Jordan's Lemma shows that the integration over $C_{\infty}$ vanishes. Thus, we have
$$\frac{1}{2\pi}\oint_C\frac{e^{i\omega t}}{a+i\omega}d\omega=\frac{1}{2\pi}\int_{-\infty}^{\infty}\frac{e^{i\omega t}}{a+i\omega}d\omega$$
The contour integral is equal to $2\pi i$ times the (only) residue at $\omega =ia$. The residue is straightforward to compute and given by $-i e^{-at}$.
Thus, for $t>0$,
$$H(\omega)=e^{-at}$$
Case 2: $t<0$
Observe the integral over $C$, where $C$ is comprised of the real line plus an infinite semi-circle, $C_{\infty}$, enclosing the lower-half plane of the complex $\omega $ plane.
$$\frac{1}{2\pi}\oint_C\frac{e^{i\omega t}}{a+i\omega}d\omega=\frac{1}{2\pi}\int_{-\infty}^{\infty}\frac{e^{i\omega t}}{a+i\omega}d\omega+\int_{C_{\infty}}\frac{e^{i\omega t}}{a+i\omega}d\omega$$
Use of Jordan's Lemma shows that the integration over $C_{\infty}$ vanishes. Thus, we have
$$\frac{1}{2\pi}\oint_C\frac{e^{i\omega t}}{a+i\omega}d\omega=\frac{1}{2\pi}\int_{-\infty}^{\infty}\frac{e^{i\omega t}}{a+i\omega}d\omega$$
The contour integral is equal to $2\pi i$ times the residue in the lower-half plane. However, there is no singularity in the lower-half plane and the residue is trivially zero.
Thus, for $t<0$,
$$H(\omega)=0$$