First Proof
Define a new random variable $Y = X - \frac{c}{2}$. It is easy to know that
$$
Var(Y) = Var(X)
$$
by using the fact $Var(X+a)=Var(X)$. Thus we only need to show $$Var(Y) \leq \frac{c^2}{4}$$
Since $0 \leq X \leq c$, we have
$$
-\frac{c}{2} \leq Y \leq \frac{c}{2}
$$
thus
$$
E[Y^2] \leq \frac{c^2}{4}
$$
Therefore,
$$
Var(Y) = E[Y^2] - (E[Y])^2 \leq \frac{c^2}{4} - (E[Y])^2 \leq \frac{c^2}{4}
$$
Another Proof
We first prove that
$E[X^2] \leq cE[X]
$. This is easy since $E[X^2] \leq E[cX] = cE[X]$.
We next prove that $Var(X) \leq \frac{c^2}{4}$. Note that
$$
Var(X) = E[X^2] - E[X]^2 \leq c(E[X] - \frac{E[X]^2}{c}) \tag{1}
$$
Moreover,
\begin{align}
&(2E[X] - c)^2 \\
=\ &4E[x]^2 - 4cE[x] + c^2 \\
=\ &4c(\frac{E[X]^2}{c} - E[x] + \frac{c}{4}) \\
\geq\ &0
\end{align}
thus, we have
$$
E[X] - \frac{E[X]^2}{c} \leq \frac{c}{4} \tag{2}
$$
According to (1) and (2), it is proved.