An intrinsic property is one that can be defined only in terms of the first fundamental form.
Taking our surface element to be $$f:U \to {\mathbb{R}^3}$$
We can parameterize f in terms of just two arbitrary coordinates (Even though the surface element is embedded in 3-space you don't need 3 coordinates to describe it)
$$f(u,v) = \left( {x(u,v),y(u,v),z(u,v)} \right)$$
We can than use this parametrization to define the first fundamental form
$${g_{ij}} = \left( {\begin{array}{*{20}{c}}
E&F \\
F&G
\end{array}} \right) = \left( {\begin{array}{*{20}{c}}
{\left\langle {\frac{{\partial f}}{{\partial u}},\frac{{\partial f}}{{\partial u}}} \right\rangle }&{\left\langle {\frac{{\partial f}}{{\partial u}},\frac{{\partial f}}{{\partial v}}} \right\rangle } \\
{\left\langle {\frac{{\partial f}}{{\partial v}},\frac{{\partial f}}{{\partial u}}} \right\rangle }&{\left\langle {\frac{{\partial f}}{{\partial v}},\frac{{\partial f}}{{\partial v}}} \right\rangle }
\end{array}} \right)$$
The arc length is than defined by just the first fundamental form and is therefore an intrinsic property
$$d{s^2} = Ed{u^2} + 2Fdudv + Gd{v^2}$$
$$L = \int\limits_a^b {ds} = \int\limits_a^b {\sqrt {Ed{u^2} + 2Fdudv + Gd{v^2}} } $$
Conceptual Example:
If you want to think about it terms of some ant that exists only in 2-space: This ant could travel the distance of some arc on a surface element and measure this distance without any knowledge of the ambient space, only knowledge of a 2-coordinate system it defines on the surface element.
Mathematical Example:
The unit 2-sphere can be parametrized in terms of only 2 coordinates, the angles phi and theta.
$$f(\varphi ,\theta ) = \left( {\cos \varphi \cos \theta ,\sin \varphi \cos \theta ,\sin \theta } \right)$$
We can than define the first fundamental form as
$${g_{ij}} = \left( {\begin{array}{*{20}{c}}
{{{\cos }^2}\theta }&0 \\
0&1
\end{array}} \right)$$
And therefore the arclength as
$$L = \int\limits_a^b {ds} = \int\limits_a^b {\sqrt {{{\cos }^2}\theta d{\varphi ^2} + d{\theta ^2}} } $$
Definition of arc length independent of any specific ambient space:
To define the length of some arc on a hyper-surface element independent of the ambient space in which the element is embedded you can use Riemannian Geometry.
Take the metric tensor: $${g_{ij}} = {e_i} \bullet {e_j}$$
And the Line Element/Riemannian Metric:
$$d{s^2} = {g_{ij}}d{x^i} \otimes d{x^j} = g$$
We can than define Arc Length in a way that is the same for all spaces in which the hyper-surface element could be embedded:
$$L = \int\limits_a^b {\sqrt {g} } $$