You mean semisimple as a module over itself. Examples include
- Any field. More generally, any division ring.
- If $R$ is semisimple, then so is $M_n(R)$ (exercise). Hence, for example, $M_n(\mathbb{R})$ is semisimple.
- If $R$ and $S$ are semisimple, then so is $R \times S$ (exercise).
It follows that any ring which is a finite product of matrix rings over division rings is semisimple. By the Artin-Wedderburn theorem, this exhausts all possibilities. In particular, $\mathbb{Z}$ is not semisimple: it is not semisimple as a module over itself because it has nontrivial submodules, such as $2 \mathbb{Z}$, which don't have complements.
In practice, a common source of examples of semisimple rings come from finite groups: if $k$ is a field and $G$ is a finite group of order not divisible by the characteristic of $k$, then the group ring $k[G]$ is semisimple by Maschke's theorem: equivalently, the category of $G$-representations over $k$ is semisimple.
See this blog post for a longer discussion with proofs.