You know that these equations will not show explicit solutions and numerical methods should be used.
The simplest would be Newton method which, starting from a "reasonable" guess $r_0$ will update it according to $$r_{n+1}=r_n-\frac{f(r_n)}{f'(r_n)}$$ We know that $r$ is small; so let us start at $r_0=0$.
For the first equation, the successive iterates would be $$r_1=0.029640$$ $$r_2=0.030716$$ $$r_3=0.030718$$ which is the solution for five significant figures.
For the second equation, the successive iterates would be $$r_1=0.029485$$ $$r_2=0.031144$$ $$r_3=0.031150$$ which is the solution for five significant figures.
Another way for a better estimate is to approximate the function by its simplest Pade approximant; built at $r=0$ this will give $r\approx 0.030705$ for the first equation and $r\approx 0.031140$ for the second equation.
Doing this on paper could be something hard; a good calculator should do it and any software so (Excel could be the easiest solution).
Since the procedures I described require derivatives (and, for these cases, they are awful) I suggest you compute them by finite differences. This will make life easier.
Edit
The first equation is much more simple than it looks. After some rearrangements, it write $$a = b e^{-\alpha r}+ c e^{-\beta r}$$ and the approximate solution given by the simplest Pade approximant is $$r=\frac{2 (-a+b+c) (\alpha b+\beta c)}{\alpha ^2 b (a+b-c)+\beta ^2 c (a-b+c)+4
\alpha \beta b c}$$ For the case considered $$a=106.065$$ $$b=\frac{6.25}{e^{0.0177\times 0.88}}\approx 6.153404241$$ $$c=\frac{106.25}{e^{-0.0059\times 1.88}}\approx 107.4350853$$ $$\alpha=0.25\times0.88=0.22$$ $$\beta=1.25\times 1.88=2.35$$ Applying the last formula, the result is $r\approx 0.0307045 $.