Let $\mathsf A$ be an abelian category and $\mathsf{K(A)}$ be the homotopy category of chain complexes over $\mathsf A$. Let $P_\bullet,Q_\bullet$ be projective resolutions of $A,B\in \mathsf A$ respectively. The fundamental lemma of homological algebra says $\mathsf{Hom}_\mathsf{A}(A,B)\cong [P_\bullet,Q_\bullet]$. This means that the set map taking an object of $\mathsf A$ to the homotopy class of its projective resolutions extends to a functor $P:\mathsf A\rightarrow \mathsf{K(A)}$. (See page 16 these notes.)
By homotopy invariance, chain homology lifts to $\mathsf{K(A)}$. In particular, we have a functor $H_0:\mathsf{K(A)}\rightarrow \mathsf A$.
Is $P \dashv H_0$?