Let $X_n$ be the number of white balls in poll $1$. Then $X_n\in\{0,1,2,3\}$. The probability transition matrix is
$$
\begin{bmatrix}
0 & 1 & 0 & 0 \\
1/9 & 4/9 & 4/9 & 0 \\
0 & 4/9 & 4/9 & 1/9 \\
0 & 0 & 1 & 0 \\
\end{bmatrix}
$$
How is this derived? Take the entries in row $2$, for example, and let WB denote the event "choose White from poll $1$ and Black from poll $2$" and so on. Then,
\begin{eqnarray*}
P(X_n=0\mid X_{n-1}=1) &=& P(\text{WB}) = \dfrac{1}{3}\cdot\dfrac{1}{3} = \dfrac{1}{9} \\
&& \\
P(X_n=1\mid X_{n-1}=1) &=& P(\text{WW} \cup \text{BB}) = \dfrac{1}{3}\cdot\dfrac{2}{3} + \dfrac{2}{3}\cdot\dfrac{1}{3} = \dfrac{4}{9} \\
&& \\
P(X_n=2\mid X_{n-1}=1) &=& P(\text{BW}) = \dfrac{2}{3}\cdot\dfrac{2}{3} = \dfrac{4}{9} \\
&& \\
P(X_n=3\mid X_{n-1}=1) &=& 0.
\end{eqnarray*}