Write $|X|$ to mean the cardinality of the set $X$. You want to show that $|\mathbb N|<|\mathbb Z\times\mathbb R|$. In fact, something stronger is true: $|\mathbb R|\leq|\mathbb Z\times\mathbb R|$.
In general, we show that $|X|\leq|Y|$ by finding an injective function from $X$ to $Y$. (This is one definition of $|X|\leq|Y|$.) Can you think of an injective function from $\mathbb R$ to $\mathbb Z\times\mathbb R$? That is, can you find a way to match every element of $\mathbb R$ up with an element of $\mathbb Z\times\mathbb R$ without overlapping matches?