This question takes inspiration from this question.
A tautology is organic if none of it's proper sub-formulas are tautologies. In other words, if all of the sub-formulas excluding the formula itself are not tautologies.
For example, C C p q C C q r C p r is organic, but C p C q C r q is not, since C q C r q is a tautology.
I suspect that there exist infinitely many organic tautologies which are not substitution instances of other tautologies. How might that get proved?