Your answer to the first part of the question is correct.
Your answer to the second seems to reflect some fundamental misunderstanding. $L(G(a^2))$ is the set of all words generated by the grammar $G(a^2)$, which has the two productions $S\to aSb$ and $S\to a^3b$. Every derivation must consist in applying the first of these productions some number of times and then applying the second one once: after each application of $S\to aSb$ we still have the non-terminal symbol $S$, so we need to apply another production, and after one application of $S\to a^3b$ we no longer have any non-terminal symbol. Suppose that we apply the first production $n$ times, where $n$ can be any non-negative integer; at that point we’ll have generated $a^nSb^n$. If we then apply the second production, the $S$ will be replaced by $a^3b$, and we’ll have $a^{n+3}b^{n+1}$. Every word of this form can be generated by $G(a^2)$, and these are the only words that can be so generated. Thus,
$$L(G(a^2))=\{a^{n+3}b^{n+1}:n\ge 0\}=\{a^{n+2}b^n:n\ge 1\}\;.$$
In words, the language consists of all words consisting of a string of $a$s followed by a string of $b$s, where there is at least one $b$, and the number of $a$s is $2$ more than the number of $b$s.
We can approach the third part of the question similarly. Whatever $w$ is, if we apply the production $S\to aSb$ $n$ times, we’ll have $a^nSb^n$, and if we then apply the production $S\to awb$, we’ll have $a^{n+1}wb^{n+1}$. Thus,
$$L(G(w))=\{a^{n+1}wb^{n+1}:n\ge 0\}\;.$$
We want to choose $w$ so that this is equal to $L=\{a^nb^{n+k}:n\ge 2\text{ and }k\ge 0\}$. However, this is impossible. Whatever $w$ is, it’s a single word, so it has a definite number of $a$s and a definite number of $b$s. Say that $w$ contains $n_a$ $a$s and $n_b$ $b$s. Then a word $a^{n+1}wb^{n+1}$ of $L(G(w))$ contains $n+1+n_a$ $a$s and $n+1+b_b$ $b$s, and the number of $b$s minus the number of $a$s is
$$(n+1+n_b)-(n+1+n_a)=n_b-n_a\;.$$
This is a constant: it’s the same for every word in the language $L(G(w))$. Now look at an arbitrary word $a^nb^{n+k}\in L$: the number of $b$s minus the number of $a$s is
$$(n+k)-n=k\;,$$
where $k$ can be any non-negative integer. If we choose $k\ne n_b-n_a$, $a^nb^{n+k}$ will be a word in the language $L$ that is not in $L(G(w))$, so $L(G(w))\ne L$. We can make this argument for any $w\in\Sigma^*$, so there is no $w$ such that $L(G(w))=L$.
Now see if you can use the same ideas to solve the fourth part. From what we just did, you know that whatever $w$ may be,
$$L(G(w))=\{a^{n+1}wb^{n+1}:n\ge 0\}\;.$$
For what values of $w$ will this set include the word $a^3b^3$?