Assuming that you have $n$ data points $(x_i,y_i)$, the fit of the model $$y=a^x+b^x$$ (which is nonlinear) requires reasonable estimates of parameters $a$ and $b$ to start the nonlinear regression.
Suppose that the data are not in too much error. You can probably find among the data points two of them $(x_1,y_1)$, $(x_2,y_2)$ such that $x_2\approx 2x_1$. So, we can look at two equations $$y_1=a^{x_1}+b^{x_1}$$ $$y_2=a^{x_2}+b^{x_2}\approx a^{2x_1}+b^{2x_1}$$ Defining $A=a^{x_1}$, $B=b^{x_1}$, this give as equations $$y_1=A+B$$ $$y_2=A^2+B^2$$ Elimintaing $A$ for the first equation and replacing in the second equation leads to a quadratic in $B$ $$2 B^2-2 B {y_1}+(y_1^2-y_2)=0 $$ and then the solutions are $$A=\frac{1}{2} \left({y_1}-\sqrt{2 {y_2}-{y_1}^2}\right)$$ $$B=\frac{1}{2} \left({y_1}+\sqrt{2 {y_2}-{y_1}^2}\right)$$ from which $a=A^{1/x_1}$, $b=B^{1/x_1}$.
Let us try with JJacquelin's data points; using the $10^{th}$ and $20^{th}$ data points, we obtain $a=0.122$ and $b=1.488$. Starting the nonlinear regression with these initial values should be reasonable.
Using the whole set of data points, the iterative process converge in a small number of iterations and leads to $$y=0.100644^x+1.50081^x$$ to which corresponds $R^2=0.999828$ which shows an almost perfect fit of the data.
Edit
As marty cohen suggested, if $x_2\approx 3x_1$, doing the same as above, the equation in $B$ remains a quadratic (since the $B^3$ terms has the good idea to disappear) $$3 {y_1}B^2-3 {y_1^2}B+({y_1^3}-{y_2})=0$$ and gives $$B=\frac{ \sqrt{3y_1(4 y_2-y_1^3)}+3 y_1^2}{6 y_1}$$ Using the $5^{th}$ and $15^{th}$ data points, we obtain $a=0.083$ and $b=1.516$