Yes, and more is true: given any positive rational number $n$, there exists a finite set $M\subset\Bbb N$ such that $\sum_{k\in M} \frac1k = n$.
Perhaps the most straightforward proof is this: since the harmonic series diverges, there exists a unique $m\in\Bbb N$ such that
$$
\sum_{k=1}^m \frac1k \le n < \sum_{k=1}^{m+1} \frac1k.
$$
(If $n$ is small then $m$ might equal $0$.)
Write $r=n-\sum_{k=1}^m \frac1k$, which is a rational number less than $\frac1{m+1}$. Then use the greedy algorithm to write $r$ as an Egyptian fraction $\sum_{k\in M_r} \frac1k$. By size considerations, every element of $M_r$ exceeds $m$, and so $M=\{1,\dots,m\} \cup M_r$ has the property that $\sum_{k\in M} \frac1k = n$.
Similar constructions can yield representations of $n$ with particular constraints; for example, one can choose any $j\in\Bbb N$ and force all the elements of $M$ to exceed $j$.