WLOG assume that $a_1<a_2<a_3<a_4$. Then
$$a_3+a_4>a_1+a_2 \implies a_3+a_4>\frac{1}{2}S \implies (a_3+a_4)\nmid S$$
and
$$a_2+a_4>a_1+a_3 \implies a_2+a_4>\frac{1}{2}S \implies (a_2+a_4)\nmid S$$
So two of the six possible combinations definitely don't divide the sum. So $n_A$ is at most four.
We have maximal $n_A=4$, because there is a solution for $n_A=4$, namely
$$(a_1,a_2,a_3,a_4)=k(1,5,7,11),\quad k\in\mathbb{Z}^+$$
This was constructed by trial and error after noting that if $n_A=4$ then:
- either $a_1+a_4$ or $a_2+a_3$ exceeds $\frac{1}{2}S$ (hence cannot divide) unless $a_1+a_4=a_2+a_3=\frac{1}{2}S$
- $a_1+a_2<a_1+a_3<a_1+a_4$ so $S$ is a higher multiple of $(a_1+a_2)$ than it is of $(a_1+a_3)$, and is a higher multiple of $(a_1+a_3)$ than it is of $a_1+a_4$
So first try with multiples of $2$, $3$ and $4$, resulting in the set of simultaneous equations
$$\begin{array}{rcccc}
S=&2a_1&&&+2a_4 \\
S=&&2a_2&+2a_3 \\
S=&3a_1&&+3a_3 \\
S=&4a_1&+4a_2 \\
\end{array}$$
This solves to $a_1=\frac{S}{24},a_2=\frac{5S}{24},a_3=\frac{7S}{24},a_4=\frac{11S}{24}$.
Since the $a_i$ must be integral, take $S=24k,a_1=k,a_2=5k,a_3=7k,a_4=11k$.
I will leave it up to the reader to see whether multiples other than $3$ and $4$ can also produce viable solutions, noting that solutions are not viable if one of the numbers (especially $a_1$) is a negative multiple of $S$.