$$\frac{(2n)!}{n!(n+1)!} = \frac{(n+2)\cdots (n+n)}{n!}$$
since for every number $k\le n$ there exists a number $m$ such that $ n+2 \le mk\le2n$, for any factor in the denominator there is that factor (and then some) in the numerator. Hence it's an integer
Here is why I don't think induction is a good idea:
$$\frac{(2k+2)!}{(k+1)!(k+2)!} = \frac{(2k+2)(2k+1)(2k)!}{(k+1)(k+2)(k+1)!k!} = \frac{(2k+2)(2k+1)}{(k+1)(k+2)} \cdot \frac{(2k)!}{(k+1)!k!} = $$$$=
\frac{2(2k+1)}{k+2} \cdot \frac{(2k)!}{(k+1)!k!}$$
Now if $\displaystyle \frac{2(2k+1)}{k+2}$ was an integer, induction would work perfectly. But it's not an integer! So you need to show somehow that $k+2$ divides the factor on the right.. But then the induction hypothesis is useless and you are better off just proving the result directly! ;-)