The symbolic expressions are there precisely to make those distinctions unambiguous. It is good that you have noticed the possibility of ambiguity, because then you're more than halfway to learning how the notation resolves that ambiguity.
It may help a bit to write down the claim with more parentheses:
$$ \forall x\in\mathbb N \Big( \exists y\in\mathbb N (x+y=0)\Big)$$
This extra set of brackets doesn't change the meaning; it is how chained quantifiers are always interpreted. Then we can unravel the quantifiers one my one.
For every natural number $x$ it is true that
$$ \exists y \in\mathbb N (x+y=0) $$
The symbolic formula $\exists y\in\mathbb N(x+y)=0$ contains the variable $x$ but does not bind that variable -- so it is an open formula that denotes a property that some specific $x$ can have or not have. Namely, the property "you can add something to it to make it zero".
In other words, the formula $\exists y\in\mathbb N(x+y=0)$ only becomes true or false when we select a value for $x$. Once we do so, it turns into one of
$$ \exists y\in\mathbb N(0+y=0) \\ \exists y\in\mathbb N(1+y=0) \\ \exists y\in\mathbb N(2+y=0) \\ \cdots $$
And the truth values of each of those doesn't care about how we produced it. Each of them can be evaluated by itself, and the $\exists y$ in one of them is independent of the fact that there's another $\exists y$ somewhere else on the paper.
Here we see that $\exists y\in\mathbb N(0+y=0)$ is true (we can take $y=0$), but the other formulas are false (there is no $y\in\mathbb N$ that becomes 0 when you add 1 or 2).
Now we can go back to the $\forall x$. It asserted that all of the different $\exists y$ formulas are true, which is not the case, and therefore the entire $\forall x\exists y\ldots$ formula is false.
What this all works out to when the dust settles is that
- When a $\exists$ appears to the right of $\forall$, the $\exists$-bound variable is allowed to depend on the $\forall$-bound variable.
- When the $\exists$ appears to the left of $\forall$, there must be a single value for the $\exists$-bound variable that works for all choices of $\forall$.
Typically you would just be asked to memorize these two shortcut rules. But I think it is easier to know how the rules arise -- namely by putting in the parentheses and treating one quantifier at a time.