Without loss of generality we can choose $a=sin^2x$ and $b=cos^2x$ for $x \in \left(0 \: \frac{\pi}{2}\right)$
Now $$a^2+b^2=sin^4x+cos^4x=1-2sin^2xcos^2x=1-\frac{sin^22x}{2}=\frac{3+cos4x}{4} \ge \frac{1}{2}$$ with Equality at $x=\frac{\pi}{4}$
Also $$2sinxcosx \le 1$$ $\implies$
$$\frac{1}{sin^4xcos^4x} \ge 16$$
Now by $CS$ Inequality $$\left(\frac{1}{a^2}+\frac{1}{b^2}\right)(1^2+1^2) \ge\left(\frac{1}{a}+\frac{1}{b}\right)^2=(sec^2x+cosec^2x)^2=(sec^2xcosec^2x)^2=sec^4xcosec^4x=\frac{1}{sin^4xcos^4x} \ge 16$$ Thus
$$\left(\frac{1}{a^2}+\frac{1}{b^2}\right)(1^2+1^2) \ge 16$$
$$\left(\frac{1}{a^2}+\frac{1}{b^2}\right) \ge 8$$
Thus $$\left(a+\frac{1}{a}\right)^2+\left(b+\frac{1}{b}\right)^2 \ge \frac{1}{2}+8+4=\frac{25}{2}$$