Let $\mathbb V\subseteq\mathbb P^n$ be a projective irreducible complex variety. Consider the rational map
\begin{align*}
\varphi\colon\mathbb V \times \mathbb V \times \mathbb P^1 &\longrightarrow \mathbb P^n\\
([x_0:\ldots:x_n],[y_0:\ldots:y_n],[t_0:t_1]) & \longmapsto [t_0x_0+t_1y_0:\ldots:t_0x_n+t_1y_n]
\end{align*}
which is defined on the open set
$$U=\{ (x,y,t) \mid x\ne y \}\subseteq \mathbb V \times \mathbb V \times \mathbb P^1.$$
Then, since $\mathbb V \times \mathbb V \times \mathbb P^1$ is irreducible, the open set $U$ is also irreducible. Therefore, $\varphi(U)$ is also an irreducible subset of $\mathbb P^n$. Note that the Secant variety of $\mathbb V$ is precisely $\overline{\varphi(U)}$. Since $\varphi(U)$ is irreducible, the Secant is therefore also irreducible and closed.