By the Mean Value Theorem applied to $f(x)=e^{1/x}$ with $f'(x)=-x^{-2}e^{1/x}$, we have
$$e^{1/\sin x}-e^{1/x}=f(\sin x)-f(x)=(x-\sin x)f'(\xi)=\frac{x-\sin x}{\xi^2}\cdot e^{1/\xi} $$
with $\xi$ between $x$ and $\sin x$.
We can find $a>0$ such that for all small enough positive $x$ we have
$$\tag1 \sin x < x -ax^3 $$
and hence
$$\frac{x-\sin x}{\xi^2}>\frac{x-\sin x}{x^2}>ax.$$
Thus for small $x$ with $t:=\frac 1t$
$$e^{1/\sin x}-e^{1/x}=\frac{x-\sin x}{\xi^2}\cdot e^{1/\xi} >axe^{1/x}=a\cdot \frac{e^t}{t}\to +\infty$$
because the exponential grows stronger than any polynomial (You might use $e^x\ge 1+x$ for all $x$ $\implies e^t=(e^{t/2})^2\ge(1+\frac t2)^2=1+t+\frac14t^2$ for all $t>-2$).
How can we show $(1)$?
Pick any $a$ with $0<a<\frac16$ and let $g(x)=x-ax^3-\sin x$.
Then $g'(x)=1-3ax^2-\cos x$, $g''(x)=-6ax+\sin x$, $g''(x)=-6a+\cos x$, so $g'''$ is strictly decreasing from positive $1-6a$ to negative $-6a$ on $[0,\frac\pi2]$ and has a unique root $x_0\in(0,\frac\pi2)$. Thus $g''$ is strictly increasing in the interval $[0,x_0]$. Then says $g''(x)> g''(0)=0$ for all $x\in (0,x_0]$, so staht $g'$ is strictly increasing in $[0,x_0]$. Thus $g'(x)>g'(0)=0$ for all $x\in(0,x_0]$, so that $g$ is strictly increasing on $[0,x_0]$.
Thus $g(x)>g(0)=0$ for $0<x\le x_0$, in other words: $(1)$.