The random variable $X$ can take on values $1$, $2$, $3$, $4$, $5$, or $6$. For all $i$ with $1\le i\le 6$, we will find $\Pr(X=i)$. It is perhaps useful to deal with them backwards.
$\Pr(X=6)$: This is the easiest one. The probability that the minimum is $6$ is the probability all the rolls are $6$. Thus $\Pr(X=6)=\left(\frac{1}{6}\right)^n$.
$\Pr(X=5)$: Next we find the probability the minimum is $5$. This happens if (i) all the throws are $\ge 5$ but (ii) not all the throws are $\ge 6$. The probability all the throws are $\ge 5$ is $\left(\frac{2}{6}\right)^n$. It follows that $\Pr(X=5)=\left(\frac{2}{6}\right)^n-\left(\frac{1}{6}\right)^n$.
$\Pr(X=4)$: Next we find the probability the minimum is $4$. This happens if (i) all the throws are $\ge 4$ but (ii) not all the throws are $\ge 5$. The probability all the throws are $\ge 4$ is $\left(\frac{3}{6}\right)^n$. It follows that $\Pr(X=4)=\left(\frac{3}{6}\right)^n-\left(\frac{2}{6}\right)^n$.
Halfway done! It's your turn.