We claim for any sphere $S^n$, there is a homotopy between the identity and the double reflection$$(x_0, x_1, x_2, \dots, x_n) \mapsto (-x_0, -x_1, x_2, \dots, x_n).$$To see this, define$$\ell: S^n \to \mathbb{R},\text{ }r(x_0, \dots, x_n) = \sqrt{x_0^2 + x_1^2},$$and$$\theta:S^n \to [0, 2\pi),\text{ }\theta(x_0, \dots, x_n) = \text{Arg}(x_0 + ix_1).$$Since$$(x_0, x_1) = (\ell(x)\cos(\theta(x)), \ell(x)\sin(\theta(x))),$$we have the homotopy$$H: S^n \times [0, \pi] \to S^n,\text{ }H(x, t) = (\ell(x)\cos(\theta(x) + t),\ell(x)\sin(\theta(x) + t),x_2, \dots, x_n)$$taking$$H(x, 0) = (x_0, x_1, x_2, \dots, x_n) \text{ to }H(x, \pi) = (-x_0, -x_1, x_2, \dots, x_n).$$In fact, there is nothing special about the indices $0$ and $1$, as this argument shows there is a homotopy between the identity and any double reflection. In particular, if $n$ is even, we have a homotopy between the identity and$$(x_0, x_1, \dots, x_n) \mapsto (x_0, -x_1, \dots, -x_n).$$Composing this homotopy with the antipodal map gives the desired homotopy between the antipodal map and the single reflection $r$.