It is simpler. Formally, don't forget that $X$ is no more than a function wich satisfies certains properties: it has a domain, a codomain (which is a vector space in most of the cases), a correspondence rule and an extra propertie (measurability, but it is not important for your question).
If $\Omega$ and $V$ is your codomain, where for all $u,v\in V$ we have $u+v$ is well defined (for example $X:\Omega\to\mathbb{R}$ for obtain a way to sum $X(w)+X(w)$), then $X+X:\Omega\to\mathbb{R}$ is, by definition, $(X+X)(w)=X(w)+X(w)$ (remember that $X(w)$ is in certain form a number. Then $X(w)+X(w)$ is a number).
Thus, all depend on whether the codomain has a sum or not, AND, if it is the case, how do you define the sum.
For example, take $U=\{A,B\}$ (letters $A$ and $B$) and $\sigma=2^U$. Now, set $\Omega=[0,1]$ with $\mathcal{F}=\mathcal{B}$, and $P:\mathcal{F}\to\mathbb{R}$ given by $P(A)=\lambda(A)$ (Lebesgue measure).
Let $X:\Omega\to U$ given by $X(w)=A$. Thus $X$ is a random variable and $(X+X)(w)=X(w)+X(w)=A+A$. But what is the value of $A+A$? $A$ is only a letter, and, at least I don't know how sum letters.