Show that $K$ is an algebraic extension over $F$ if and only if for every intermediate field $E$, every monomorphism $\sigma: E\rightarrow E$ which is the identity on $F$ is in fact an automorphism of $E$.
The $\Rightarrow$ direction seems fairly easy, and doesn't really use the fact that $K$ is algebraic: any arbitrary intermediate field $E$ is an $F$-vector space, so a linear map from $E$ to itself is injective if and only if it is surjective. Thus any $\sigma: E\rightarrow E$ which is a monomorphism and fixes $F$ is, among other things, an injective $F$-linear map, and so must be surjective. Thus it's a bijective field homomorphism, i.e. an automorphism.
The other direction is stumping me. I can figure out how to begin: let $u\in K-F$, and we want to find a polynomial over $F$ which $u$ is a root of. Since we know something about every intermediate field, let's consider $F(u)$. Now we know something about monomorphisms from $F(u)$ to $F(u)$. My problem is that I can't see any obvious monomorphism to pick. But I think if I can pick the right map, then surjectivity will allow me to find a polynomial which $u$ satisfies.
Any hints are appreciated!