One way to produce partial sums that add to $1$: Pick a natural number $N$ and write the Egyptian Fraction expansion for $\frac {N-1}N$. Then, unless $\frac 1N$ appears in that expansion, adding $\frac 1N$ to the list gets you an example.
For instance, starting from $N=347$ we get the example $$\frac 12 +\frac 13+\frac 17+\frac 1{48}+\frac 1{347}+\frac 1{10600}+\frac 1{154484400}=1$$ (happily, wolfram alpha knows how to compute Egyptian fractions).
This gives rise to a question which might be of some interest: For which natural numbers $N>1$ does $\frac 1N$ appear in the Egyptian fraction expansion of $\frac {N-1}N$? For instance $\frac 34=\frac 12+\frac 14$, or $\frac {11}{12}=\frac 12+\frac 13+\frac 1{12}$, or $\frac {83}{84}=\frac 12+\frac 13+\frac 17+\frac 1{84}$. Further searching also turned up the examples $N=3612, 6526884$. OEIS recognizes these as legs in integer Pythagorean triangles with some nice properties. Should add that my search was not at all comprehensive. Once I got the pattern from OEIS I checked higher terms in that sequence and confirmed that they had the desired property.
Edit: just to be clear, we're referring to that expansion obtained via the greedy algorithm. Egyptian expansions aren't unique and it's easy to produce examples using "non-greedy" expansions.