Find the length of an endless chain which will hang over a circular pulley
of radius a so that it is in contact with two thirds of the circumference
of the pulley?
We have two pulleys (driver and driven).
Pulley "a" is bigger than pulley (say) "b", because has contact angle of 240 degrees (two thirds of the circumference = two thirds of 360 degrees).
We don't know :
a radius
b radius
center to center distance
For the formulas involved see "The pulley problem" in:
https://en.wikipedia.org/wiki/Belt_problem
Formulas are the same for belts and chains.
So you can express total length as a function of both radii and center to center distance.