Equivalently, we would like to show $A$ has an inverse if and only if it is injective. (This is the converse of your original equivalence.)
Suppose $A$ has an inverse. Then $Ax = y$ means $A^{-1} Ax = A^{-1}y$ so $x = A^{-1}y$; so the linear map $A$ is injective.
Suppose $A: \mathbb{F}^n \to \mathbb{F}^n$ is (linear and) injective. Let $\{ e_1, \dots, e_n \}$ be a basis for the vector space $\mathbb{F}^n$. I claim that $A$ is surjective; this is enough, because we can define $A^{-1}(e_i)$ to be the vector $v$ such that $A v = e_i$.
Indeed, $A e_1, \dots, A e_n$ are linearly independent (a dependence between them would be of the form $A(\alpha_1 e_1 + \dots + \alpha_n e_n) = 0$, so $\alpha_1 e_1 + \dots + \alpha_n e_n = 0$ by injectivity), and there are $n$ of them, so they span. Therefore they are a basis for $\mathbb{F}^n$.