First, let's clarify the question, since one of the commenters was confused:
By
$$p \cdot (p^{-1} \mod q)$$ the question means to find $ p^{-1}\mod q$, transform that into the unique integer $\bar{p} \in \Bbb{N} : \bar{p} \equiv p^{-1}\mod q \wedge 0\leq \bar{p} < q$, and then multiply, in the ordinary field of integers,
$p\cdot \bar{p}$.
With that understanding in place, here is your proof that $s = p \cdot (p^{-1} \mod q) + q \cdot (q^{-1} \mod p) = pq+1$ assuming $p,q$ prime:
Lemma 1: $p \cdot (p^{-1} \mod q) \equiv 1 \mod q$. Proof: This is just the definition of the inverse, mod $q$.
Corollary 2: $s \equiv 1 \mod q$. Proof: $s = p \cdot (p^{-1} \mod q) + qk$ where $k$ is some integer (which happens to be $(q^{-1} \mod p)$) so $s \equiv 1 + 0 \mod q$.
Corollary 3: $s \equiv 1 \mod p$. This is the same statement as corollary 2, exchanging $p$ and $q$.
Lemma 4: $s \equiv 1 \mod (pq)$. This is so by corollaries 2 and 3, along with the statement that $p$ and $p$ are coprime.
Lemma 5: $s > 1$. Proof: each of the terms in $s$ is a positive integer, so $s \geq 1+1$.
Lemma 6: $p \cdot (p^{-1} \mod q) < pq$ and $q \cdot (q^{-1} \mod p) < qp$. Proof: $p^{-1} \mod q < q$; multiply both sides of that relation by $p$. Similarly for the assertion about $q \cdot (q^{-1} \mod p)$.
Corollary 7: $s = p \cdot (p^{-1} \mod q) + q \cdot (q^{-1} \mod p) < 2pq$.
Theorem: $s=pq+1$. Proof: by lemma 5 and corollary 7, $1 < s < pq$. By lemma 4, $s = kpq + 1$ for some integer $k$. The unique value of the form $kpq + 1$ between $1$ and $2pq$ is $pq+1$.
Q.E.D.