An Argument from Lie Theory
Using the Jordan-Chevalley Decomposition Theorem (for the Lie algebra $\mathfrak{sl}_n(\mathbb{C})$, which consists of traceless $n$-by-$n$ matrices), $A=t\,I+S+N$ where $t:=\frac{\text{trace}(A)}{n}$, $S$ is semisimple (i.e., diagonalizable over $\mathbb{C}$) of trace $0$ , and $N$ is nilpotent such that $SN=NS$. Then, because $t\,I$, $S$, and $N$ commute, $\exp(A)=\exp(t\,I)\,\exp(S)\,\exp(N)$. That is, $$\det\big(\exp(A)\big)=\det\big(\exp(t\,I)\big)\cdot\det\big(\exp(S)\big)\cdot\det\big(\exp(N)\big)\,.$$
Obviously, the first factor is $\det\big(\exp(t\,I)\big)=\big(\exp(t)\big)^n=\exp(nt)=\exp\big(\text{trace}(A)\big)$. The last factor is $1$ because $\exp(N)=I+M$ for some nilpotent matrix $M$ (whence the eigenvalues of $M$ are all $0$). The middle factor is $1$ because $S$ is diagonalizable as $TDT^{-1}$ for some invertible matrix $T$ and for some diagonal traceless matrix $D$. Then, $$\det\big(\exp(S)\big)=\det\big(T\exp(D)T^{-1}\big)=\det\big(\exp(D)\big)=\exp\big(\text{trace}(D)\big)=1\,.$$
Consequently, $\det\big(\exp(A)\big)=\exp\big(\text{trace}(A)\big)$.